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Copper Tripeptide-1 (GHK-Cu) is a naturally occurring copper complex of the tripeptide glycyl-L-histidyl-L-lysine

So even if GHK-cu leaks systemically, the free copper increase will be far too low to do anything meaningful systemically

It reaches the summit after having meals for 6 hours and the bottom in the morning

doi: 10.1016/j.ntt.2012.09.002

Plant Physiol 138:16731689 Chen Z, Gallie DR (2004) The ascorbic acid redox state controls guard cell signaling and stomatal movement

While there is limited information on its cardiovascular risk an updated meta-analysis, there is a doubling of cardiovascular risk compared with non-use